Angelina Jolie AJOLIEBPITTMORE052107_08_X1.jpg Fashion Week Daily is reporting that Brad Pitt photographed babymama Angelina Jolie and the kids at Chateau Miraval last week for the November cover of W magazine.

This is Brad's first time shooting a magazine cover, and it marks the second time the magazine has gotten a big exclusive with the Hollywood super couple. Back in 2005, Brad and Angie appeared in the feature "Domestic Bliss" for the July 2005 issue, which showed the two in a very intimate series of portraits, providing confirmation that they were in fact lovers.