Nicole Richie chucknicolerichie.jpg image courtesy of Byron Cohen

At first I thought this was an old picture from Kill Bill, but it's actually a shot of Nicole Richie from her guest role on NBC's hit spy thriller Chuck! As you may already know, Nicole will play Heather, a bitchy cheerleader who used to make life miserable for special agent Sarah Walker (played by Yvonne Strahovski) back in high school. Well, Heather is back and by the looks of it, she's out for blood! Nicole tells Entertainment Weekly, ''I had a stunt double, but they said I was allowed to do as much as I wanted - except for serious things."

The episode with Nicole will air in October, and if you haven't already gotten into Chuck, now would definitely be the time to catch up, as the second season premieres Monday, September 29th at 8/7c on NBC.