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Justin Bieber may have seemed like a star struck teenager at the Golden Globes (yesterday he tweeted: "Halle Berry was at my table. Badass...De Niro is the man...still kind of hard to believe who was in that room. Grateful!"), but red carpet veteran Angelina Jolie didn't appear nearly as impressed!

One of Bieber's friends did manage to snap this pic of Angie (which I'm sure Zahara and Shiloh will love) posing with Justin, who didn't remove his D&G purple sunglasses for the pic.

Sorry, Justin, but unlike Kim Kardashian, we doubt you'll be able to start a Mrs. Robinson-style fake romance with Jolie anytime soon!