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Brad Pitt and Angelina Jolie have always denied that their romance began while Pitt was still married to ex Jennifer Aniston, but a new book says otherwise.

According to Confidential: The Life of Secret Agent Turned Hollywood Tycoon Arnon Milchan, by Joseph Gelman and Meir Doron, Hollywood producer Arnon Milchan "introduced Pitt to Jolie and immediately sensed that there was a spark between them."

The couple starred in Mr. and Mrs. Smith together; Milchan was a producer on the 2005 film.

The book continues:

    "A passionate romance ensued, with one slight problem ... Pitt was married to [Aniston] ... when Aniston kicked Pitt out of the house, all hell broke loose."


According to the book, Milchan intervened ... see how after the jump.