Big Pictures Australia

Angelina Jolie and Brad Pitt attended the world premiere Unbroken at the State Theatre in Sydney, Australia on Monday evening, and not only did Hollywood's golden couple look amazing, but they spent quite a bit of time chatting with some very special guests. Brangelina struck a pose with Takamasa Ishihara and his partner Melody, and we didn't know who they were before, but now we do! (Takamasa is a Japanese rock star who often goes by the name Miyavi, and Jolie cast him as a villain in the film.)

Jolie met author and motivational speaker Turia Pitt, 24, who survived burns on 64 percent of her body after being caught in a bush fire in 2011. Turia posted a snapshot on Instagram and told reporters, "What a privilege to meet this extraordinary couple."

Jolie also met with an Australian woman, who, like the Oscar winner, underwent a double mastectomy. Jolie reportedly requested to visit with Krystal Barter at the premiere after hearing her story and learning more about the organization she works with, Pink Hope. The charity helps women suffering from breast and ovarian cancer, and in a post on their Instagram page, the group wrote, "Angelina wanted to meet our founder Krystal at the #unbrokenpremiere and what a moment it turned out to be ... So proud of all Pink Hope stands for and our amazing community."

"Angelina was absolutely humble and beautiful," Barter added in a chat with Daily Mail Australia. "She made time for each of us along with Brad Pitt. It is a moment I will always cherish and remember."