It's about time Ben Affleck and Jennifer Garner made a red carpet appearance together!

The duo posed for photos at the 85th Annual Academy Awards on Sunday evening, and Jen showed off her slimmed down bod in a purple Gucci dress, while Ben looked quite dapper in head to toe Gucci as well.

So what were their red carpet preps like? "It was mayhem at our house. Our daughter was in a spelling bee at the local rec center," Jen told E! News. "I was in hair and makeup so I couldn't take her, so Ben took her in the middle of everything. She won! Our family has already had a great day, so congratulations to our sweetie. And then she had a basketball game. Life goes on. No one really cares! It's just all about trying to keep the dogs and kids from getting stuff on the stuff."

"I was more nervous at the spelling bee than I am now, I don't know what that says," Ben added. "There was a lot of words. Let me tell you something, you and me might have been in trouble. We belong in the stands."

When Ben was not nominated for his work directing Argo, he did receive a nod as a producer, as the film is nominated for Best Picture. Think it'll win?

Reese Witherspoon stunned on the red carpet at the 85th Annual Academy Awards at the Dolby Theatre on Sunday, and she revealed that her daughter Ava helped her pick out this blue satin Louis Vuitton dress!

“I love the color of it. My daughter and I picked it out," Reese told reporters. "She said, this is a winner. She’s 13, so she definitely weighs in. She helps me pick the jewelry, makeup and everything."

Jennifer Aniston and fiance Justin Theroux posed for photos on the red carpet at the 85th Annual Academy Awards on Sunday, and she went big and bold with this prom-inspired red Valentino gown. I mean, when was the last time you saw her wearing anything but basic black or neutral tones?

"It feels very princessy. I feel like this is very King and I," Jen told Lara Spencer on the red carpet. When asked who designed her jewelry, Jen added it was her fiance. Aww!

"Today was really nice, I have to say," she said of getting ready. "We had a really fun morning and a great breakfast."

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Jennifer Lawrence strikes a pose at the 2013 Academy Awards at the Dolby Theatre in Hollywood, and the 22-year-old Best Actress nominee looked stunning in a Dior Haute Couture dress.

But was it all worth it? “Today was stressful and I had no time to eat. I’m starving,” she admitted to reporters. “I’m freaking starving,” she said, before pointing to the McDonald’s on Hollywood Boulevard. She then jokingly asked her publicist to grab her burger. “I’d eat in a bathroom at this point and someone would catch me sitting on the toilet and eating, and I’d be like, ‘What?’”

While she gets nervous and chatty and tends to babble a bit, she also revealed that she's terrified to go up onstage if she wins for her role in Silver Linings Playbook. "My biggest fear is speaking publicly. I’m so nervous about presenting, I’m trying not to think about what I would say if I won."

Wait, wasn't her Golden Globes speech one of the best we've ever heard? She certainly does a good job hiding that ... then again, she is a two-time Oscar nominee!

What did she do to herself?! We knew she was clumsy, but she really has the worst timing!

Kristen Stewart posed for photos at the 2013 Academy Awards at the Dolby Theatre in Hollywood on Sunday, and she looked gorgeous in this Reem Acra gown, but rather than wearing strappy shoes and a bunch of bling, her main accessories were two crutches!

Kristen will hit the stage as a presenter tonight, so perhaps she'll explain her mystery injury then?

Jessica Chastain worked it on the red carpet at the 2013 Academy Awards at the Dolby Theatre in Hollywood on Sunday evening, and maybe this gold Armani Prive dress will bring her a little bit of extra luck? Jessica is nominated for Best Actress for her role in Zero Dark Thirty, and she's also up against Jennifer Lawrence (Silver Linings Playbook), Emmanuelle Riva (Amour), Naomi Watts (The Impossible) and Quvenzhane Wallis (Beasts of the Southern Wild).

When asked about her sparkly metallic frock, Jessica said, “I chose it because I’m such a fan of movies. I love cinema so much and when I saw it ... It’s a very ‘Happy Birthday Mr. President.’ It reminds me of old Hollywood glamour.” Indeed it does!

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In all fairness, we know she can't help the hair -- it's for her role in the upcoming Mad Max: Fury Road flick -- but that doesn't mean that we're ok with it!

Charlize Theron hit the Oscar red carpet on Sunday in a sexy Christian Dior Haute Couture dress, but shortly after that she changed into a flowy baby pink gown for her opening number with host Seth MacFarlane and Channing Tatum. The 37-year-old actress will also be presenting on stage tonight with Dustin Hoffman.

Naomi Watts almost always nails it on the red carpet, and tonight was no exception!

The 44-year-old actress wore a futuristic sequined Armani Prive gown to the 85th Annual Academy Awards on Sunday evening, and we wouldn't think to like this dress, but on her flawless frame, we're loving it!

Naomi is nominated for Best Actress for her role in The Impossible, and she's up against Jennifer Lawrence (Silver Linings Playbook), Jessica Chastain (Zero Dark Thirty), Emmanuelle Riva (Amour), and Quvenzhane Wallis (Beasts of the Southern Wild).